我国钢铁行业清洁生产标准HJ/T189存在的问题与修订建议

2006年10月1日起实施的《清洁生产标准钢铁行业》(HJ/T189-2006)存在着一些不足之处,如不及时修订,将无法适应“十一五”期间钢铁工业的发展形势和清洁生产形势,在某种程度上还很容易对国内钢铁企业造成误导,而且会产生一些负面不良影响。根据目前我国钢铁工业的发展形势和国内外钢铁企业已经达到的实际清洁生产水平,就其存在的问题和今后的修订谈了一些看法。     

调节剂对烷基水杨醛肟萃取铜铁的影响

烷基水杨醛肟虽然是一种高选择性的铜萃取剂，但单独使用时，萃取相易出现沉淀；反萃时，再生有机相出现乳化物，而且两相分离时间较长．将月桂醇、仲辛醇、壬基酚三种调节剂分别加入到萃取剂中，研究其对烷基水杨醛肟萃取及反萃行为的影响．结果表明，三种调节剂均可以解决上述问题，只是使萃取能力略有降低；壬基酚加入到烷基水杨醛肟中有助于提高铜铁分离系数，可达647．     

天铁炼铁技术进步

近十年来，天铁集团炼铁厂通过改善原燃料条件；优化炉料结构，提高入炉品位；采用提高炉顶压力、富氧喷煤、低硅冶炼、炉顶气象系统等多项先进技术，使高炉各项经济技术指标逐年提高。     

Methacryloxyethyl phosphate‐grafted expanded polytetrafluoroethylene membranes for biomedical applications

Expanded polytetrafluoroethylene (ePTFE) membranes were modified by graft copolymerization with methacryloxyethyl phosphate (MOEP) in methanol and 2‐butanone (methyl ethyl ketone (MEK)) at ambient temperature using gamma irradiation. The effect of dose rate (0.46 and 4.6 kGy h^?1), monomer concentration (1–40 %) and solvent were studied and the modified membranes were characterized by weight increase, X‐ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). XPS was used to determine the % degree of surface coverage using the C? F (ePTFE membrane) and the C? C (MOEP graft copolymer) peaks. Grafting yield, as well as surface coverage, were found to increase with increasing monomer concentration and were significantly higher for samples grafted in MEK than in methanol solution. SEM images showed distinctly different surface morphologies for the membranes grafted in methanol (smooth) and MEK (globular), hence indicating phase separation of the homopolymer in MEK. We propose that in our system, the non‐solvent properties of MEK for the homopolymer play a more important role than solvent chain transfer reactions in determining grafting outcomes. Copyright © 2005 Society of Chemical Industry     

曲轴激光喷丸强化试验研究

采用实验的方法,研究了激光冲击强化对175A型柴油机曲轴疲劳寿命的影响,取得了激光冲击强化试验条件下曲轴过渡圆角处残余应力场的数据。并将激光冲击强化工艺效果和曲轴滚压强化效果做了对比性分析,结果表明：虽然激光冲击强化效果不如曲轴滚压强化,但考虑到激光工艺参数精确可控、加工质量好、成本低以及可避免滚压强化所造成的表面疲劳、撕痕等,激光冲击强化工艺可望代替滚压强化成为新型的曲轴强化手段。通过此类激光冲击强化强化实验可优化激光冲击的相关参数,使曲轴过渡圆角产生有利的残余应力场。     

磷酸酯淀粉在纯棉细特高密织物浆纱中的应用

就磷酸酯淀粉在纯棉细号高密织物中的上浆情况进行了试验，提出了具体浆纱工艺和减少织造断头率，提高织物效率及布面质量对策，实验表明，磷酸酯淀粉完全适应于纯绵细特高密织物的上浆要求。     

Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.     

汽车发动机电机铁芯用钢(ADW2)的研制开发

鞍钢研制开发的汽车发动机启动电机用钢是针对汽车电机铁芯用钢（定、转子）而开发的电机钢类产品。介绍了该产品的研制过程及规格、特点。通过批量试制及装机试验，产品巳满足用户的使用要求。     

油气田开发中的CO2腐蚀及防护技术

综述了二氧化碳均匀腐蚀和局部腐蚀的机理，分析了二氧化碳腐蚀的各种影响因素，并对二氧化碳腐蚀的防护技术进行了概括，着重介绍了缓蚀剂防护技术研究进展，并提出了研究CO2腐蚀及其缓蚀剂应注意的几个问题。     

Action of chelators on solid iron in phosphate-containing aqueous solutions

To study the effect of strong iron-ligands on steel corrosion, mild steel electrodes were immersed in solutions containing 20 mM phosphate buffer (pH=7.2) and between 0.01 mM and 1 M of either the iron(II)-chelators 2,2^′-bipyridine or FerroZine, or the iron(III)-chelators citrate or acetylacetonate. Resulting surface reactions were investigated by quantifying the electrochemical potential (E), the electrochemical polarization resistance (R_p), the corrosion current (I_corr) and the release of iron into solution. The surface was further analyzed by scanning electron microscopy (SEM/SEM-EDAX) and atomic force microscopy. Concentrations of 0.1 mM of any of the chelators led to slight, temporary changes in E, I_corr and R_p. Concentrations of 10 mM resulted in characteristic changes of E, which were the same for all chelators and in the precipitation of FePO₄ in the case of citrate and acetylacetonate, or vivianite [Fe₃(PO₄)₂ · 8H₂O] in the case of bipyridine and FerroZine. Concentrations of 1 mM of both iron(III)-chelators led to a temporary drop of E similar to that found with 0.1 mM chelator. With iron(II)-chelators, E dropped to about −500 mV before oscillating for several days. The amplitudes of the oscillations were up to 200 mV with periods of 30 and 20-25 min for bipyridine and FerroZine, respectively.